February 24, 2010
In August of 2009 in Truckee, CA, a man was cooking on a stove when the pan caught fire, activating the fire sprinklers. Upon activation of the sprinklers, a violent explosion occurred which resulted in 1 death and 4 burn injuries to the family.
I came across this copy of a report (from the IAFSS mailing list) which details a report of a cooking fire turned explosive when the sprinklers were activated. Allegedly the propylene glycol used in the fire sprinkler system as an antifreeze aided in the explosive event, and another case is cited in which the antifreeze ignited and assisted in growing the fire from its ignition source.
The report can be found here: California –explosion– report (PDF)
While I have taken a few courses in fire sprinkler systems, I am not extremely familiar with the flammability of antifreeze such as propylene glycol, but allegedly the atomization of the droplets causing the liquid to become flammable was the cause of this explosion. More flammability and MSDS hazard info is cited in the report.
The report presents many questions at the end which would be useful in quantifying the relationship of the antifreeze in this case, especially since (to my understanding) propylene glycol is the most widely used antifreeze in sprinkler systems. I look forward to finding out more about this topic, and I think it’d be a great research project for a student or research firm to take on.
February 24, 2010
My M.S. in Fire Protection Engineering from WPI was recently confirmed and my M.S. thesis was released for publication. The title of the thesis is “Characterizing the Flammability of Storage Commodities Using an Experimentally Determined B-number”.
Link to thesis is here: http://www.wpi.edu/Pubs/ETD/Available/etd-121409-192436/
The abstract is as follows:
In warehouse storage applications, it is important to classify the burning behavior of commodities and rank them according to material flammability for early fire detection and suppression operations. In this study, the large-scale effects of warehouse fires are decoupled into separate processes of heat and mass transfer. As a first step, two nondimensional parameters are shown to govern the physical phenomena at the large-scale, a mass transfer number, and the soot yield of the fuel which controls the radiation observed in the large-scale. In this study, a methodology is developed to obtain a mass-transfer parameter using mass-loss (burning rate) measurements from bench-scale tests. Two fuels are considered, corrugated cardboard and polystyrene. Corrugated cardboard provides a source of flaming combustion in a warehouse and is usually the first item to ignite and sustain flame spread. Polystyrene is typically used as the most hazardous product in large-scale fire testing. A mixed fuel sample (corrugated cardboard backed by polystyrene) was also tested to assess the feasibility of ranking mixed commodities using the bench-scale test method. The nondimensional mass transfer number was then used to model upward flame propagation on 20-30 foot stacks of Class III commodity consisting of paper cups packed in corrugated cardboard boxes on rack-storage. Good agreement was observed between the model and large-scale experiments during the initial stages of fire growth.